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The unreleased track marks the first song Porter and Etheridge have written together in ten years.
The Oklahoma singer-songwriter reeled off the hits from his expansive catalogue at Brooklyn's Barclays Center.
The star-studded duet appears on Brown's new studio album, ‘The High Road’, which arrives on January 24th.
The collaboration, which was produced by Dr Dre, appears on Snoop Dogg's new album, ‘Missionary’.
The much-loved country extravaganza will also feature the likes of Taylor Holder, Meghan Patrick, Harper O’Neill and Reyna Roberts.
Theo also brought his gym buddies along as the group heartwarmingly serenaded Music City residents.